Document Type
Article
Publication Date
2009
Abstract
The title material crystallises in the triclinic crystal system in space group P-1 with Z = 2. The unit cell dimensions are a = 8.7365(6)AÅã, b = 10.6009(7)AÅã, c = 12.0210(8)AÅã with α = 66.343(1)Åã, β = 79.566(1)Åã, γ = 83.150(1)Åã and V = 1001.6(1)AÅã3. The final R value is 0.0307 (3905 observed reflections: I >2σ(I)). The compound is best described as a species in which each metal atom is coordinated to two dithiocarbamato groups, one of which forms a secondary bridging interaction (through a S-atom) to a second [Zn(S2CNEtPh)2] unit. Thus, the title material is in the form of a dimeric aggregate. This complex is compared to related materials which contain N-atoms within the dithiocarbamato ligand that are derived from secondary amines containing two different organic functionalities.
Recommended Citation
Gossage, Robert A. and Jenkins, Hilary A., "The Crystal Structure of bis-(μ-N-ethyl-Nphenyldithiocarbamato- S,S’)-bis[(N-ethyl-Nphenyldithiocarbamato- κ2S,S’)zinc(II)]" (2009). Chemistry and Biology Research and Publications. Paper 3.
http://digitalcommons.ryerson.ca/chem/3
Comments
Acta Chim. Slov. 2009, 56, 329–333.
Publisher URL: http://acta.chem-soc.si/56/56-2-329.pdf